Organotin compounds in the environment an overview of the book

The emphasis of this chapter and this book is on tributyltin tbt, the principal. What is the situation with agrochemicals and how are they used. High amounts of the toxic tributyltin and some other organotin derivatives can be found not only in water and sediments, but also various aquatic organisms and. Abstractdue to the extensive use of organotin compounds otcs in. The emphasis of this chapter and this book is on tributyltin tbt, the principal biocidal ingredient of most organotin antifouling paints. For more than 50 years, organotin compounds have been used in almost all sectors of industry. Pdf organotin compounds and environment researchgate. Organotins are organometallic compounds based on organic derivatives of the tetravalent tin, such as methyl, butyl, octyl, phenyl organotins, and others. Organometallic compounds in the environment wiley online. As a consequence, specific parts of the environment are affected by the emission of these xenobiotics.

The need for research on environmental effects will grow concomitant with. Pdf organotin compound that have at least one snc bond have wide commercial. The process gives high yields but the use of high amounts of solvents is required. The commercial production of organotin compounds by using the grignard reagent nr mgcl fig.

This has given rise to an increase of the worldwide production of organotin compounds during the. Pdf organotin compounds in the environment francesca. The high toxicity of trisubstituted derivatives towards aquatic organisms has resulted in. Emma popek, in sampling and analysis of environmental chemical pollutants second edition, 2018. Download citation organotin compounds in the environment an overview tin. Pdf organotin compounds in the environment an overview. Tin has a larger number of its organometallic derivatives in commercial use than any other element. The impact of organotin compounds in the environment is assessed, based on a critical survey of the published literature. Pdf history on organotin compounds, from snails to humans. A useful resource for all researchers and scientists in industry working with organometallic compounds, including, chemists, environmentalists and ecologists. Concerning organometallic compounds in environment intechopen.

This has given rise to an increase of the worldwide production of organotin compounds during the last 50 years. In environment, most of organometallic compounds were found as persistent that do not easily decompose but are easily concentrated and are. History on organotin compounds, from snails to humans. Organotin compounds in the environment an overview.

It is also a summary of the environmental effects of organotin compounds on. Due to the wide industrial applications considerable amounts of the organotins have entered various ecosystems. After a brief introduction, the properties and characteristics of organotin compounds are outlined, with notes on methods of manufacture, patterns of use and chemical properties. It is also a summary of the environmental effects of organotin compounds on nontarget organisms, ranging from oyster shell thickening and growth anomalies to imposex in the common dogwhelk nucella. If n3, the compound has the highest toxicity, for example etesnoac has ld so 4mgkg rats and this is the most toxic compound. While sn in its inorganic form is considered to be nontoxic, the toxicological pattern of the organotin compounds is complex. Overview of decay rates of tbt and other organotins in water and sediments. An introduction to organotin compounds and their use in antifouling coatings.

Organotin compounds in the environment organometallic. A proposal for health and environmental hazard classification of dioctyl and dibutyl tin compounds is under discussion within the eu. It is the more valuable because research on tbt has often been published in less accessible journals and symposium proceedings. Organotin compounds are also utilized commercially in polymers in film for food.

Organotin compounds affect natural killer nk on lymphocytes in human. Review organotin compounds in the environment an overview. It will help to minimize the duplication of research and speed the introduction of legislation around the world to control organotin pollution. Organotin compounds have demonstrated significant economic benefits, as well as environmental costs, as a result of their varied industrial and agricultural uses and applications. This book provides an overview of the induction mechanism of imposex caused by organotin compounds in gastropods, as well as fundamental information on the physiology and biochemistry of reproduction in mollusks. Organotin compound an overview sciencedirect topics. Organotin compounds are ubiquitous contaminants in the environment. Methods for the analysis of organotin speciation in the environment.